报告地点：宝山东校区材料楼520室
报告时间：2015.11.06下午13：30
Recent Advances in the Chemistry of an Isolable Silylene
Mitsuo Kira
mkira@m.tohoku.ac.jp
Whereas silicon divalent species (silylenes) are usually generated as reactive intermediates in numerous thermal and photochemical reactions of organosilicon compounds, 1 has been available as a sole isolable dialkylsilylene since 1999.1 Silylene 1 has been revealed not only to be valuable to undestand unique bonding and properties of silylene but also useful as a regaent for the synthesis of hardly accesible unsaturated silicon compounds including silaketeneimines, a silanethione, and a trisilaallene.
In the present talk, some recent studies of its new reactions with carbon -hetroatom doubly bonded compounds such as imines, benzonitriles, diazocarbonyl compounds, and carbon dioxide and their mechanistic aspects are discussed, in addition to a brief summary of the synthesis, structure, and properties of 1.
References
(1) Kira, M.; Ishida, S.; Iwamoto, T.; Kabuto, C. J. Am. Chem. Soc. 1999, 121, 9722. (2) Kira, M.; Iwamoto, T.; Ishida, S. Bull. Chem. Soc. Jpn. 2007, 80, 258. (3) Kira, M., Chem. Commun. 2010, 46, 2893 (Feature Article). (4) Kira, M. J. Chem. Sci. 2012, 124, 1205.